胡椒アミドおよびびその関連類縁体の合成と殺虫活性

  • 宮門 正和
    Pesticides Research Laboratory, Takarazuka Research Center, Sumitomo Chemical Co., Ltd.
  • 中山 勇
    Pesticides Research Laboratory, Takarazuka Research Center, Sumitomo Chemical Co., Ltd.
  • 井上 歩
    Pesticides Research Laboratory, Takarazuka Research Center, Sumitomo Chemical Co., Ltd.
  • 波多腰 信
    Pesticides Research Laboratory, Takarazuka Research Center, Sumitomo Chemical Co., Ltd.
  • 大野 信夫
    Pesticides Research Laboratory, Takarazuka Research Center, Sumitomo Chemical Co., Ltd.

書誌事項

タイトル別名
  • Chemistry and Insecticidal Activities of <i>Piperaceae</i> Amides and Their Synthetic Analogues
  • 胡椒アミドおよびその関連類縁体の合成と殺虫活性〔英文〕
  • コショウ アミド オヨビ ソノ カンレン ルイエンタイ ノ ゴウセイ ト サッ
  • The <i>Piperaceae</i> Amides (Part 6)

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説明

The present paper describes the synthetic methods of dihydropipercide [N-isobutyl-11-(3, 4-methylenedioxyphenyl)-(2E, 4E)-2, 4-undecadienamide] analogues and their structure-insecticidal activity relationships with respect to the amine and the carbon chain moieties. It has been discovered that the terminal benzyl group could be replaced by a phenoxy group without loss of activity and N-isobutyl-12-(3, 4-methylenedioxyphenoxy)-3-methyl-(2E, 4E)-2, 4-dodecadienamide was selected as the most potent insecticidal amide in this group against Callosobruchus chinensis (adzuki bean weevil). This amide also revealed noticeable toxicities against Chilo suppressalis (rice stem borer) as well as Musca domestica (housefly).

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