β-Si<sub>3</sub>N<sub>4</sub>結晶モフォロジーの制御とそのメカニズム (第2報)

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タイトル別名
  • Control of .BETA.-Si3N4 Crystal Morphology and Its Mechanism. (Part 2). Effect of Lanthanide Additives.
  • Control of β-Si3N4 Crystal Morphology and Its Mechanism(Part2)Effect of Lanthanide Additives
  • Control of ベーターSi3N4 Crystal Morphology and Its Mechanism Part2 Effect of Lanthanide Additives
  • Effect of Lanthanide Additives

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説明

Alpha-Si3N4 powder mixed with SiO2 and Ln2O3 (Ln=La, Gd or Yb) was heat-treated at 1750-1900°C. After removing the glassy phase, the morphologies of β-Si3N4 crystals were quantitatively analyzed. The aspect ratios of β-Si3N4 crystals doped with different lanthanide oxides increased in the order of La2O3>Gd2O3>Yb2O3 at high annealing temperatures. The anisotropic Ostwald ripening model successfully simulated grain growth behaviors of β-Si3N4 with different lanthanide additives, and suggested that the observed difference in grain growth behaviors be due to the change in the reaction rate at the (100) interface between the β-Si3N4 crystal and the Ln-Si-O-N liquid phase.

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