固液反応法によるCdS粉末及び膜の合成

  • 大友 良則
    成蹊大学工学部応用化学科無機材料工学研究室
  • 川崎 兼司
    成蹊大学工学部応用化学科無機材料工学研究室
  • 尾崎 義治
    成蹊大学工学部応用化学科無機材料工学研究室

書誌事項

タイトル別名
  • Synthesis of CdS Powder and Film by Solid-Liquid Reaction and Fabrication of Its Thick Film.
  • コエキ ハンノウホウ ニ ヨル CdS フンマツ オヨビ マク ノ ゴウセイ

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抄録

Fine cadmium sulfide (CdS) powder was prepared from metal alkoxide. Using this powder, CdS films were fabricated. The CdS films were investigated using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The CdS powder was synthesized by sulfurization of Cd(OR)2 (R=CH3, C2H5) or Cd(OH)2, and Cd(OH)2 was derived from the hydrolysis of Cd(OR)2. CdS pastes were manufactured by dispersing the resultant CdS powder into a mixture of terpineol and ethylcellulose using a three-roll mill. CdS pastes were screen-printed on glass substrates and dried. The CdS films were heat-treated at 300-600°C in a N2 atmosphere, and examined by XRD. Preferred orientation in the [002] direction was observed for CdS films obtained from Cd(OH)2. On the other hand, in the case of CdS films obtained from Cd(OR)2, no preferred orientation was observed.

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