New Intergrowth Bi2WO6-Bi3TaTiO9 Ferroelectrics.
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- NOGUCHI Yuji
- Department of Applied Chemistry, School of Engineering, The University of Tokyo
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- SATOH Rikiya
- Department of Applied Chemistry, School of Engineering, The University of Tokyo
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- MIYAYAMA Masaru
- Institute of Industrial Science, The University of Tokyo
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- KUDO Tetsuichi
- Institute of Industrial Science, The University of Tokyo
Bibliographic Information
- Other Title
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- 新規交代層強誘電体Bi<sub>2</sub>WO<sub>6</sub>-Bi<sub>3</sub>TaTiO<sub>9</sub>
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Abstract
A new intergrowth bismuth layer-structured ferroelectric, Bi2WO6-Bi3TaTiO9 (BW-BTT), was successfully synthesized by solid-state reaction, and the regular intergrowth structure was confirmed by the Rietveld method. Differential thermal analysis measurements suggested that the BW-BTT underwent ferroelectric phase transitions twice at around the Curie temperatures of the constituent compounds of BW and BTT. The structural analysis of the BW-BTT showed that there are two kinds of Bi ions in the bismuth oxide layers, and that one Bi ion was displaced to the polarization direction by about 2% of the lattice constant a from the corresponding position in the parent tetragonal structure. This displacement of Bi in the bismuth oxide layers is the structural feature which was found for the first time for both conventional and intergrowth bismuth layered structures.
Journal
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 109 (1265), 29-32, 2001
The Ceramic Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282680226356992
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- NII Article ID
- 110002288818
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- NII Book ID
- AN10040326
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- ISSN
- 18821022
- 09145400
- http://id.crossref.org/issn/09145400
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- NDL BIB ID
- 5620564
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed