光学活性アトロプ異性アニリド誘導体の合成と不斉反応への応用

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タイトル別名
  • Synthesis of Optically Active Atropisomeric Anilide Derivatives and Their Application to Asymmetric Reaction.
  • コウガク カッセイ アトロプ イセイ アニリド ユウドウタイ ノ ゴウセイ ト フセイ ハンノウ エ ノ オウヨウ

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N-Substituted anilide derivatives bearing a large substitutent such as a tent-Bu group at the ortho-position have atropisomerism due to the high rotation barrier of the N-Ar bond and resist racemization. We have succeeded in the synthesis of such atropisomeric N-Ar amides, imides and lactams with high optically purity and definite absolute configuration, and the development of various asymmetric reactions using them. Furthermore, catalytic asymmetric reaction with such atropisomeric anilide as a chiral ligand is also described.

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