Approaches to Catalytic Asymmetric Formation and Reactions of Lithium Enolates.
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- Koga Kenji
- Faculty of Pharmaceutical Sciences, University of Tokyo
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- Shindo Mitsuru
- Faculty of Pharmaceutical Sciences, University of Tokyo
書誌事項
- タイトル別名
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- Approaches to Catalytic Asymmetric Form
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Studies have been made to explore the use of chiral chelated lithium amides or their corresponding amines for enantioselective reactions. Some of our results are discussed in terms of enantioselective deprotonation of prochiral cyclic ketones, kinetic resolution of racemic 2-substituted cyclohexanones, regioselective deprotonation of optically active 3-keto steroids, enantioselective alkylation and protonation of achiral lithium enolates. Examples of catalytic asymmetric deprotonation and alkylation by the present strategy are also discussed.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 53 (11), 1021-1032, 1995
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390282680253224832
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- NII論文ID
- 10001716445
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- NII書誌ID
- AN0024521X
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- COI
- 1:CAS:528:DyaK2MXpsVGisrs%3D
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- ISSN
- 18836526
- 00379980
- http://id.crossref.org/issn/00379980
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- NDL書誌ID
- 3640575
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可