Asymmetric Synthesis of Axially Chiral Biaryls Utilizing Planar Chiral Arene Chromium Complexes.

DOI Web Site 参考文献76件
  • Kamikawa Ken
    Department of Chemistry, Faculty of Integrated Arts and Sciences, Osaka Prefecture University
  • Watanabe Takashi
    Department of Chemistry, Faculty of Integrated Arts and Sciences, Osaka Prefecture University
  • Uemura Motokazu
    Department of Chemistry, Faculty of Integrated Arts and Sciences, Osaka Prefecture University

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Axially chiral biaryls are stereoselectively prepared by utilizing planar chiral arene chromium complexes. Both enantiomers of an axial biaryl could be synthesized starting from a single enantiopure arene chromium complex, and this method is applied to the synthesis of the vancomycin A-B ring system and korupensamines.

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