Studies on the chemistry of mitomycins.

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  • KONO Motomichi
    Pharmaceutical Research Laboratories, Kyowa HakkoKogyo Co., Ltd.
  • KASAI Masaji
    Pharmaceutical Research Laboratories, Kyowa HakkoKogyo Co., Ltd.

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  • マイトマイシン類の化学研究
  • マイトマイシンルイ ノ カガク ケンキュウ

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Abstract

The studies on the chemistry of mitomycins are described : i) identification and structural elucidation of mitomycins D, E, F, G, I, J, K, L, M, albomitomycin A, and isomitomycin A from the fermentation broth; ii) derivation of mitomycins structurally close to naturally occurring mitomycins; iii) mitomycin rearrangement, the interconversion between mitomycin A, albomitomycin A, and isomitomycin A;iv) chemical con-version of isomitomycin A from mitomycin A; v) 3α-alkoxymitomycins, unexpected by-products in decarbamoylation of mitomycins;vi) the configuration of mitiromycin.

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