Generation and Synthetic Utilization of Highly Reactive Fluorinated Intermediates.

  • UNEYAMA Kenji
    Department of Applied Chemistry, Faculty of Engineering, Okayama University

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  • 高活性含フッ素中間体の創製とフッ素官能基の導入
  • コウ カッセイ ガン フッソ チュウカンタイ ノ ソウセイ ト フッソ カンノ

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Abstract

Generation and synthetic utilization of highly reactive fluorinated intermediates, which include chemistries of trifluoroacetimidoyl halides, electrochemical activation of fluorinated organic compounds, and chalcogen molecule mediated fluorinations, are discussed.<BR>Synthesis of optically active trifluoroalanine via trifluoroacetimidoyl palladium intermediates, generation of trifluoroacetimidoyl radicals, electrochemical synthesis of 2-CF3-benzimidazoles, chemistry of benzeneselenenyl fluoride, and SET process between benzeneselenolate anion and fluorinated alkylhalides are highlight of this overview.

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