書誌事項
- タイトル別名
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- Structure of Spherical Porous Silica Particles Derived from Tetramethoxysilane and Methyltrimethoxysilane
- ケイサン メチル ト メチルトリメトキシシラン カラ ゴウセイシタ キュウジョ
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Spherical porous silica particles were synthesized by the sol-gel process from tetramethoxysilane and methyltrimethoxysilane in W/O emulsion. The difference in structure change by calcination is remarkable between air and nitrogen atmospheres. By calcination of the particles under N2 gas atmosphere their pore structures can be maintained up to 1000°C. This is due to the fact that Si-CH3 bond remains at high temperature. The 29Si MAS NMR spectra revealed that the intensity of T3 structural unit, whose origin is Si-C bonding, increased with an increase in methyltrimethoxysilane in a starting solution.
収録刊行物
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- Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌)
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Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌) 105 (1220), 335-340, 1997
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390282680254658432
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- NII論文ID
- 110002289160
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- NII書誌ID
- AN10040326
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- ISSN
- 18821022
- 09145400
- http://id.crossref.org/issn/09145400
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- NDL書誌ID
- 4184884
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可