Structure of Spherical Porous Silica Particles Derived from Tetramethoxysilane and Methyltrimethoxysilane
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- YAMASHITA Hiroshi
- Department of Applied Chemistry, Faculty of Engineering, Ehime University
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- TANIGUCHI Tomohiro
- Department of Applied Chemistry, Faculty of Engineering, Ehime University
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- TANAKA Kanako
- Department of Applied Chemistry, Faculty of Engineering, Ehime University
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- MAEKAWA Takashi
- Department of Applied Chemistry, Faculty of Engineering, Ehime University
Bibliographic Information
- Other Title
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- ケイ酸メチルとメチルトリメトキシシランから合成した球状多孔質シリカの構造
- ケイサン メチル ト メチルトリメトキシシラン カラ ゴウセイシタ キュウジョ
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Abstract
Spherical porous silica particles were synthesized by the sol-gel process from tetramethoxysilane and methyltrimethoxysilane in W/O emulsion. The difference in structure change by calcination is remarkable between air and nitrogen atmospheres. By calcination of the particles under N2 gas atmosphere their pore structures can be maintained up to 1000°C. This is due to the fact that Si-CH3 bond remains at high temperature. The 29Si MAS NMR spectra revealed that the intensity of T3 structural unit, whose origin is Si-C bonding, increased with an increase in methyltrimethoxysilane in a starting solution.
Journal
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 105 (1220), 335-340, 1997
The Ceramic Society of Japan
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Details 詳細情報について
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- CRID
- 1390282680254658432
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- NII Article ID
- 110002289160
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- NII Book ID
- AN10040326
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- ISSN
- 18821022
- 09145400
- http://id.crossref.org/issn/09145400
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- NDL BIB ID
- 4184884
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed