HREM Study of Oxygen-Defective LaMnO<sub>3-<i>x</i></sub> with Twin Structure
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- SHIBAHARA Hiroyasu
- Department of Chemistry and Material Science, Kyoto University of Education
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- NUMAGUCHI Kazuhiko
- Department of Chemistry and Material Science, Kyoto University of Education
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- SEO Noriko
- Department of Chemistry and Material Science, Kyoto University of Education
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- KAWASAKI Masahiro
- JEOL Ltd.
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- IBE Katsuhiko
- JEOL Ltd.
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- TAGUCHI Hideki
- Research Laboratory for Surface Science, Faculty of Science, Okayama University
Bibliographic Information
- Other Title
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- 双晶構造を含む酸素欠損型LaMnO<sub>3-<i>x</i></sub>の高分解能電子顕微鏡観察
- HREM Study of Oxygen Defective LaMnO3-x
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Abstract
Oxygen-defective LaMnO3-x with twin structure was studied using an HREM. On the basis of direct observation with a 200-kV HREM and with the aid of computer simulation, an optimum imaging condition was found, where metal La and Mn atoms and oxygen atoms were imaged as dark spots and bright spots, respectively. The through-focus observation and intensity profile observed from the image contrast support the view that the oxygen vacancies could be detected from the intensity distribution of bright spots in the observed image, which represents the positions of the oxygen atoms. A structure image under the optimum imaging condition reflected the twin structure with oxygen vacancies in LaMnO3-x. Twin structures were found to consist of two kinds of twin planes, (110) and (112), including oxygen vacancies.
Journal
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 104 (1205), 11-16, 1996
The Ceramic Society of Japan
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Details 詳細情報について
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- CRID
- 1390282680255239808
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- NII Article ID
- 110002291302
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- NII Book ID
- AN10040326
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- ISSN
- 18821022
- 09145400
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- NDL BIB ID
- 3917986
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed