書誌事項
- タイトル別名
-
- Chirality Organization Induced by Self-Assembling Properties of Amino Acid Units.
- アミノサン ユニット ノ カイゴウ トクセイ ニ モトヅク フセイ コウゾウ ユウキ
この論文をさがす
説明
Introduction of amino acid units into a ferrocene or 2, 6-pyridinedicarboxamide scaffold has been demonstrated to form an ordered structure in both solid and solution states. Conformational enantiomerization through chirality organization was achieved. The single-crystal X-ray structure determination of the ferrocene bearing the podand chiral dipeptide chains (-L-Ala-L-Pro-OEt) and the D-derivative revealed two C2-symmetrical intramolecular interchain hydrogen bondings to induce the chirality organized structures. The molecular structures of the L- and D-isomer are in a good mirror image relationship based on conformational enantiomers. The single-crystal X-ray structure determination of the chiral 2, 6-pyridinedicarboxamide bearing the podand L-histidyl moieties and the D-derivative confirmed a left- and right-handed helical conformation, respectively, through intramolecular hydrogen bonding and chirality of the podand histidyl moieties. The propensity to form the chiral helicity appears to be controlled by the configuration of the histidyl α-carbon atoms. These chiral 2, 6-pyridinedicarboxamides were found to induce the chiral complexation.
収録刊行物
-
- 有機合成化学協会誌
-
有機合成化学協会誌 59 (12), 1195-1203, 2001
公益社団法人 有機合成化学協会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390282680255672320
-
- NII論文ID
- 10012285654
-
- NII書誌ID
- AN0024521X
-
- ISSN
- 18836526
- 00379980
-
- NDL書誌ID
- 6002620
-
- 本文言語コード
- ja
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可