Surface-mediated photoalignment of organic/inorganic nanohybrids
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- SEKI Takahiro
- Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University
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- FUKUMOTO Haruhiko
- Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University
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- HARA Mitsuo
- Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University
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- KAWATSUKI Nobuhiro
- Department of Materials Science and Chemistry, Graduate School of Engineering, University of Hyogo
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- NAGANO Shusaku
- Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University
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抄録
Light irradiation provides significant tools for material structuring and processing. In this article, the photo-orientation processes of the organic/inorganic hybrid materials recently achieved in our laboratory are briefly introduced. Irradiation of linearly polarized light to a polymer film containing a photoisomerizabke azobenzene or photocrosslinkable cinnamoyl unit leads to the induction of anisotropic molecular orientations on the surface. This molecular anisotropic surface structure can be transferred to a controlled orientation of nanostructures of organic/inorganic hybrid films at macroscopic scales. Two classes of lyotropic/silica systems have been applied to the photo-orientation procedures, i.e., ordinary surfactant systems and chromonic ones. These processes can be regarded as the extended applications of the so-called command surface systems, which photochemically regulate the molecular orientations of liquid crystals.<br>
収録刊行物
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 116 (1351), 361-368, 2008
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390282680259911680
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- NII論文ID
- 110006623951
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- NII書誌ID
- AA12229489
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- ISSN
- 13486535
- 18820743
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- NDL書誌ID
- 9396987
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可