Preparation of hectorite-like swelling silicate with controlled layer charge density

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  • OGAWA Makoto
    Department of Earth Sciences, Waseda University Graduate School of Science and Engineering, Waseda University
  • MATSUTOMO Takayuki
    Graduate School of Science and Engineering, Waseda University
  • OKADA Tomohiko
    Department of Chemistry and Material Engineering, Faculty of Engineering, Shinshu University

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Smectite like layered silicates with cation exchange capacity ranges from 60 to 90 mequivalent/100g clay were synthesized from LiF, Mg(OH)2 and colloidal silica. The controlled cation exchange capacity achieved by changing the composition of the starting mixture (namely the added LiF amount) successfully influenced the nanostructures of intercalation compounds prepared by the ion exchange with dioctadecyldimethylammonium ion.

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