Study of the morphotropic phase boundary in the lead-free Na1/2Bi1/2TiO3-BaTiO3 system by Raman spectroscopy
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- ROUT Dibyaranjan
- Materials Interface Laboratory, Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology
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- MOON Kyoung-Seok
- Materials Interface Laboratory, Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology
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- RAO V. Shankar
- Materials Interface Laboratory, Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology
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- KANG Suk-Joong L.
- Materials Interface Laboratory, Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology
書誌事項
- タイトル別名
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- Study of the morphotropic phase boundary in the lead-free Na<sub>1/2</sub>Bi<sub>1/2</sub>TiO<sub>3</sub>-BaTiO<sub>3</sub> system by Raman spectroscopy
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Lead-free piezoelectric (100-x)Na1/2Bi1/2TiO3-xBaTiO3 solid solution ceramics are investigated by Raman spectroscopy and X-ray diffraction over a composition range of 0 ≤ x ≤ 10. Distinct changes in the Raman spectra and X-ray diffraction patterns were discussed in the light of a rhombohedral to tetragonal phase transition. The dominant bands in the Raman spectra were analyzed by observing the changes in their respective peak positions, widths and intensities as the composition increased. Based on these results, it is suggested that the morphotropic phase boundary in the studied system lies at the composition of x ≈ 5.5. This is further evidenced by the X-ray diffraction analysis.
収録刊行物
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 117 (1367), 797-800, 2009
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390282680261039872
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- NII論文ID
- 10025968446
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- NII書誌ID
- AA12229489
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- ISSN
- 13486535
- 18820743
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- NDL書誌ID
- 10265486
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可