The 62th CerSJ Awards for Academic Achievement in Ceramic Science and Technology: review: Synthesis of high-performance ceramics based on polymerizable complex method
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- KAKIHANA Masato
- Institute of Multidisciplinary Research for Advanced Materials, Tohoku University
書誌事項
- タイトル別名
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- Synthesis of high-performance ceramics based on polymerizable complex method
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The polymerizable complex (PC) method was developed to prepare copper-based high-Tc superconducting oxides with improved superconducting properties, phosphor materials with excellent emission intensities and water-splitting photocatalysts with higher activities. The PC method is based on the formation of metal complexes and subsequent polyesterification between a hydroxy-caroboxylic acid such as citric acid and a glycol such as propylene glycol, so that homogeneity of the metal species inside the polyester resin precursor is maintained on the molecular scale. An example of Y2SiO5:Ce3+,Tb3+ co-activated phosphor synthesis utilizing a new water soluble silicon compound is provided. The PC method is also an efficient methodology for the preparation of promising compounds for testing, without the requirement of tailoring the synthesis for each candidate; a scheme to search for the potential Tm3+ activated phosphors in the series of complex gallates as hosts has been demonstrated as a representative example.
収録刊行物
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 117 (1368), 857-862, 2009
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390282680261835776
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- NII論文ID
- 10025968656
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- NII書誌ID
- AA12229489
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- COI
- 1:CAS:528:DC%2BD1MXhtVaqtbfK
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- ISSN
- 13486535
- 18820743
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- NDL書誌ID
- 10298432
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可
