Effect of Mn doping on the leakage current and polarization properties in K0.14Na0.86NbO3 ferroelectric single crystals
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- NOGUCHI Yuji
- Research Center for Advanced Science and Technology, The University of Tokyo
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- MIYAYAMA Masaru
- Research Center for Advanced Science and Technology, The University of Tokyo
書誌事項
- タイトル別名
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- Effect of Mn doping on the leakage current and polarization properties in K<sub>0.14</sub>Na<sub>0.86</sub>NbO<sub>3</sub> ferroelectric single crystals
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Single crystals of K0.14Na0.86NbO3 (KNN) and Mn-substituted KNN (Mn-KNN, K0.14Na0.86Mn0.005Nb0.995Oy) were grown by a flux method, and the effects of Mn substitution on the leakage current, polarization and dielectric properties were investigated along [100]cubic. As-grown and annealed (850°C in air) crystals did not show an apparent polarization hysteresis loop due to its large leakage current density (∼10−3 A/cm2). The annealing at 1100°C in air led to a marked decrease in leakage current density of the order of ∼10−6 A/cm2 for KNN crystals. Mn-KNN crystals annealed at 1100°C in air exhibited a low leakage current density of ∼10−8 A/cm2. Electron spin resonance measurements and defect chemistry analysis show that the average valence increase of Mn by oxidation treatment (the annealing in air) absorbs electron hole, the carrier of the leakage current, which is suggested to be the origin of the low leakage current observed for Mn-KNN crystals.
収録刊行物
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 118 (1380), 711-716, 2010
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390282680262240896
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- NII論文ID
- 130000304622
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- NII書誌ID
- AA12229489
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- ISSN
- 13486535
- 18820743
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- NDL書誌ID
- 10770774
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可