Preparation and fluorescence properties of novel alkaline earth silicate phosphors by reduction treatment of Eu3+ to Eu2+
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- KAMEI Shinnosuke
- Department of Materials and Applied Chemistry, Faculty of Science and Engineering, Nihon University
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- KOJIMA Yoshiyuki
- Department of Materials and Applied Chemistry, Faculty of Science and Engineering, Nihon University
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- NISHIMIYA Nobuyuki
- Department of Materials and Applied Chemistry, Faculty of Science and Engineering, Nihon University
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抄録
The synthesis and emission spectrum control of novel Eu2+-activated amorphous alkaline earth silicate phosphors from the reduction of Eu3+-activated amorphous alkaline earth silicate phosphors is reported. The as-prepared Eu3+-activated amorphous alkaline earth silicate phosphors emitted red. Reduction using Ni-metal powder in a H2 (5%)/Ar (95%) atmosphere produced Eu2+-activated amorphous barium silicate phosphor that emitted green. Eu2+-activated amorphous calcium silicate was produced by reduction with ammonium chloride in air and emitted purple-blue. It was possible to control the emission spectrum by changing the reduction time. These results suggest the possibility to use three-band type phosphors for the fabrication of white light emitting diodes using one host crystal.
収録刊行物
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 118 (1380), 758-761, 2010
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390282680262359296
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- NII論文ID
- 130000304633
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- NII書誌ID
- AA12229489
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- ISSN
- 13486535
- 18820743
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- NDL書誌ID
- 10770881
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可