A direct synthesis of the styrylimido derivative of the hexamolybdate dianion

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  • FISCHER Jeffrey
    Department of Chemical & Materials Engineering, The University of Idaho
  • STAMPKA Tiffany
    Department of Chemical & Materials Engineering, The University of Idaho
  • ROLL Mark F.
    Department of Chemical & Materials Engineering, The University of Idaho

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Description

Polyoxometalate imides represent an area of materials chemistry research that recently has seen exciting exploration. Consisting of polyhedral metal-oxide clusters covalently coupled to organic ligands, they possess a combination of electrochemical activity and poly-anionic character hint. These characteristics suggest significant opportunities in the area solid-electrolytes, particularly if the typically good film forming characteristics of hybrid polymers can be accessed. The incorporation of a styryl group allows for hybrid polymers to be synthesized through free radical methods, producing hybrid materials that offer that an enormous number of opportunities to both materials scientists and engineers. This Note will document a concise route to quickly produce the readily polymerizable, styrylimido-hexamolybdate monomer from low cost precursor materials by leveraging recent advances and address some of the synthetic challenges found.

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