Millimeter-wave dielectrics of indialite/cordierite glass ceramics: Estimating Si/Al ordering by volume and covalency of Si/Al octahedron

DOI Web Site 被引用文献3件 参考文献8件 オープンアクセス
  • OHSATO Hitoshi
    Department of Research, Nagoya Industrial Science Research Institute
  • KIM Jeong-Seog
    Department of Material Science and Engineering, Hoseo University
  • CHEON Chae-Il
    Department of Material Science and Engineering, Hoseo University
  • KAGOMIYA Isao
    Material Science and Engineering, Nagoya Institute of Technology

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説明

Cordierite (Mg2Al4Si5O18) is a candidate for millimeter-wave dielectrics, and has two polymorphs due to ordering of Si and Al ions on Si/AlO4 tetrahedra: disordered high symmetry form called as indialite and ordered low symmetry form cordierite. Indialite/cordierite glass ceramics exhibited much higher Qf value of 200,000 GHz than conventional solid state reaction ceramics of 40,000 GHz, which were fabricated by crystallization of glass pellet. The glass ceramics having indialite as a dominant phase showed high Qf. The crystal phases are analyzed by Rietveld method. In this paper, the ordering ratios of indialite and cordierite are estimated by the volumes and covalencies of Si/AlO4 tetrahedra.

収録刊行物

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