Composition dependence of crystal structure and electrical properties for epitaxial films of Bi(Zn1/2Ti1/2)O3-BiFeO3 solid solution system
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- YAZAWA Keisuke
- Department of Innovative and Engineered Materials, Tokyo Institute of Technology
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- YASUI Shintaro
- Department of Innovative and Engineered Materials, Tokyo Institute of Technology
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- MORIOKA Hitoshi
- Department of Innovative and Engineered Materials, Tokyo Institute of Technology Application Laboratory, Bruker AXS
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- YAMADA Tomoaki
- Department of Innovative and Engineered Materials, Tokyo Institute of Technology
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- UCHIDA Hiroshi
- Department of Materials and Life Sciences, Sophia University
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- GRUVERMAN Alexei
- Department of Physics and Astronomy, University of Nebraska–Lincoln
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- FUNAKUBO Hiroshi
- Department of Innovative and Engineered Materials, Tokyo Institute of Technology
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Epitaxial xBi(Zn1/2Ti1/2)O3–(1 − x)BiFeO3 films were grown on (100)cSrRuO3//(100)SrTiO3 substrates by metal organic chemical vapor deposition (MOCVD). The effects of x value on the crystal structure and the electrical properties were investigated. Constituent phase changed from rhombohedral symmetry to two types of tetragonal ones with different unit cell volume and tetragonality. Rhombohedral phase and the tetragonal phase with smaller tetragonality were not ascertained to transform to cubic phase up to 800°C from high temperature XRD results. Relative dielectric constant measured at room temperature showed the maximum value at x = 0.21 near the phase boundary between tetragonal and rhombohedral symmetries. Leakage current became small when the measurement temperature decreased at 80 K and the ferroelectricity monotonously decreased with increasing x values and was not ascertained above 0.26.
収録刊行物
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 118 (1380), 659-663, 2010
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390282680263641216
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- NII論文ID
- 130000304611
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- NII書誌ID
- AA12229489
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- ISSN
- 13486535
- 18820743
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- NDL書誌ID
- 10770692
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 使用不可