Synthesis, structure and properties of new functional oxynitride ceramics

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  • The 66th CerSJ Awards for Advancements in Ceramic Science and Technology : Synthesis, structure and properties of new functional oxynitride ceramics

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Abstract

Novel metal oxynitrtides have been prepared by nitridation of amorphous metal oxide precursors obtained through citrate route. Their crystal structure, especially in O/N distribution and local bonding characteristics has been analyzed by using neutron diffraction, X-ray absorption and transmission electron microscopy, to investigate their electric and optical properties. In dielectric SrTaO2N, crystal structure refinement suggested the short range O/N ordering and local tilting of cis-TaO4N2 octahedra, resulting in its unusual large permittivity. Its dense ceramics were sintered with SrCO3 additive and exhibited superior dielectric constant above 1 × 104 at room temperature. New biphasic wurtzite and zinc-blende structure of gallium oxynitride nanowire was observed by using transmission electron microscopy. As-grown long gallium oxynitride nanowire exhibited a characteristic broad UV emission at 4.3 eV in its cathodoluminescene spectrum. New oxynitride phosphor having magnetoplumbite structure, LaAl12(O,N)19:Eu showed photoluminescence emission peak splitting due to Eu2+ site splitting to two crystallographic sites induced by the two kinds of anions in its crystal structure.

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