Diffusion behavior of Ag electrodes into (Bi<sub>1/2</sub>K<sub>1/2</sub>)TiO<sub>3</sub> ceramics
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- IWAGAMI Naoki
- Faculty of Science and Technology, Tokyo University of Science
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- NAGATA Hajime
- Faculty of Science and Technology, Tokyo University of Science
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- SAKAGUCHI Isao
- National Institute for Materials Science
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- TAKENAKA Tadashi
- Faculty of Science and Technology, Tokyo University of Science
Abstract
The diffusion of silver, Ag, as the electrode material in (Bi1/2K1/2)TiO3 (BKT) ceramic were studied by means of a secondary ion mass spectrometry (SIMS). Some analytical methods of SIMS were applied to obtain Ag diffusion coefficient in BKT ceramics. Depth profile of Ag showed a simple concentration gradient from the surface towards the deeper side in BKT ceramics. From these profiles, the diffusion coefficients of Ag were calculated and obtained by the analysis. The temperature dependence of Ag diffusion in BKT ceramics was described by 2.2 × 106 cm2/s of pre-exponential factor and 296 kJ/mol of the activation energy in the temperature range of 700–900°C as diffusion treatments.
Journal
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 123 (1439), 615-617, 2015
The Ceramic Society of Japan
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Details 詳細情報について
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- CRID
- 1390282680264803456
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- NII Article ID
- 130005085528
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- ISSN
- 13486535
- 18820743
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- Text Lang
- ja
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed