-
- 阿部 正明
- 九州大学大学院工学研究院応用化学部門
書誌事項
- タイトル別名
-
- Mixed-Valency and Metal-Metal Coupling in Polynuclear Metal Complexes: Recent Progress and Prospects
この論文をさがす
抄録
Recent progress in the redox chemistry of multimetallic transition-metal complexes and clusters is reviewed. Special attention is paid to high-nuclearity complexes wherein redox-active sites (e.g., ferrocenyl pendants or Ru centers) are assembled in a close proximity with a well-defined geometry via the covalent or coordination bonds. A special emphasis is placed on literature survey for paddlewheel diruthenium(II,III) complexes coordinated by axial or equatorial ferrocenyl ligands, polyferrocenyl compounds in the form of wire, star, and ring, ferrocenyl-based dendrimers, and ligand-mediated molecular triangles and squares. Finally, future prospects of these mixed-valent systems are briefly discussed.
収録刊行物
-
- Bulletin of Japan Society of Coordination Chemistry
-
Bulletin of Japan Society of Coordination Chemistry 58 20-32, 2011
錯体化学会