金属錯体の配位環境制御による機能発現

DOI 参考文献109件 オープンアクセス

書誌事項

タイトル別名
  • Unique Functions of Metal Complexes Inspired by Control of Coordination Environment around Metal Ions

抄録

Biological functions in metallo-enzymes are induced by the unique first and secondary coordination spheres around the metal ions of active centers. We designed and prepared some structural and functional model complexes with their unique coordination spheres, such as oxygenases, oxidases, tyrosinase, hemocyanine, hemerythrin, methane monooxygenase, nitrile hydratase, photosynthesis, nitrogenase, siderophore, and so on, and tried not only basic elucidations of their structure-function relationships but also industrial development of their functions. Here we describe some examples as follows; (i) from the stable capture of active oxygen species to their activations, (ii) from the selective preparations of bis((μ-oxo)dicopper(III) and μ-η 22-peroxo dicopper(II) complexes to clarification of tyrosinase function, (iii) from hemerythrin functional model (reversible dioxygen binding) to cathode of fuel cell (four-electron reduction of dioxygen), and (iv) from the construction of nitrile hydratase functional model to NO sensor.

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詳細情報 詳細情報について

  • CRID
    1390282680274813568
  • NII論文ID
    130004688198
  • DOI
    10.4019/bjscc.63.2
  • ISSN
    18831737
    18826954
  • 本文言語コード
    en
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
    • KAKEN
  • 抄録ライセンスフラグ
    使用不可

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