水の酸化分子触媒の新展開

  • 八木 政行
    新潟大学大学院自然科学研究科・科学技術振興機構

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タイトル別名
  • New Development of molecular catalysts for water oxidation
  • ミズ ノ サンカ ブンシ ショクバイ ノ シン テンカイ

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Artificial photosynthesis is expected as one of promising clean energy-providing systems in future. Development of an efficient catalyst for water oxidation to evolve O2 is a key task to yield a breakthrough for construction of an artificial photosynthetic device. Recently, significant progress has been reported in development of the molecular catalysts for water oxidation based on manganese, ruthenium and iridium complexes. The molecular aspects of the catalysts in chemical, electrochemical, and photo- or photoelectro-driven water oxidation were reviewed to provide hints to design an efficient catalyst. This review will mainly cover the related progress in the last 5 or 6 years.

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