Harmony of π-π Stacking Interaction and Metal Complexation to Generate Molecular Functional Emergence
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- Yamada Yasuyuki
- Department of Chemistry, Graduate School of Science, Nagoya University
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- Tanaka Kentaro
- Department of Chemistry, Graduate School of Science, Nagoya University
Bibliographic Information
- Other Title
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- π-πスタッキング相互作用と金属錯体形成が織りなす分子機能のハーモニー
- p-pスタッキング ソウゴ サヨウ ト キンゾク サクタイ ケイセイ ガ オリナス ブンシ キノウ ノ ハーモニー
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Abstract
In this review, we focus on the integrated assemblies of metal complexes and their functional emergence generated by the synergy effects of π-π stacking interaction and metal complexation. Programmable construction of integrated molecular assemblies is the best measure for bringing out the emergent functions which can be evolved from the intermolecular communications of functional molecular components. Combination of π-π stacking interaction and metal complexation allows not only to reinforce the mutual interactions but also to generate the emergent intermolecular communications. This review introduces the recent studies including the synergy effects on electrical, magnetic, catalytic and molecular recognition functions in soft, crystalline and single molecular materials.
Journal
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- Bulletin of Japan Society of Coordination Chemistry
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Bulletin of Japan Society of Coordination Chemistry 62 (0), 12-22, 2013
Japan Society of Coordination Chemistry