Transformation of Inorganic Sulfurs Using Rhodium/Iridium Dinuclear Complexes
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- Isobe Kiyoshi
- Graduate School of Natural Science & Technology, Kanazawa University
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- Nakai Hidetaka
- Graduate School of Natural Science & Technology, Kanazawa University
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- Kojima Shota
- Graduate School of Natural Science & Technology, Kanazawa University
Bibliographic Information
- Other Title
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- ロジウムおよびイリジウム二核錯体による無機硫黄の変換
- ロジウム オヨビ イリジウム 2カク サクタイ ニ ヨル ムキ イオウ ノ ヘンカン
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Abstract
In this article, we report unique reactivities of hydrogensulfide (SH), disulfide (S2), and oxydisulfide ligands (S2On: n = 1-4) bridging between the Rh—Rh/Ir—Ir bonds. The hydrogensulfide and the disulfide ligand give rise to the S—C and C—C bond formation and the multi C—Cl bond activation, respectively. The oxydisulfide ligand (S2O4) shows a photoisomerization resulting in an intriguing crystalline-state photochromism. These reactivities are attributed mainly to the electron-rich Rh—Rh/Ir—Ir bond and the geometrical arrangement and the electronic character of the sulfide ligands.
Journal
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- Bulletin of Japan Society of Coordination Chemistry
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Bulletin of Japan Society of Coordination Chemistry 50 2-17, 2007
Japan Society of Coordination Chemistry