Studies on the Tetramer of Chlorcyan and its Derivatives. II.

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  • ク自ルシアンの四量体およびその誘導体に関する研究(第2報)
  • クロルシアン ノ ヨンリョウタイ オヨビ ソノ ユウドウタイ ニ カンスル ケンキュウ 2
  • Syntheses of chloroiminoethers and urethanes from the tetramer of chlorcyan and aliphatic alcohols.
  • クロルシアン四量体と脂肪族アルコールとからクロルイミノエーテルおよびウレタン類の合成

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The reaction of chlorocyan tetramer (2, 4-dichloro-6-isocyanodichloro-1, 3, 5-triazine) with aliphatic alcohol has been investigated and it was found that a chloroimino ether type new compound (2, 4-dichloro-6-alkoxychloroisocyano-1, 3, 5-triazine) was produced by substitution of a chlorine in isocyanodichloro group in the side chain with an alkoxyl group with good yield, remaining a chlorine in triazine ring unchanged. Hydrolysis of this chloroimino ether type compound gave a new urethane type compound (2, 4-dichloro-6-alkoxycarbonylamino-1, 3, 5-triazine) with good yield.

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