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- 小松 紘一
- 京都大学工学部石油化学教室
書誌事項
- タイトル別名
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- Stable carbocations having the intramolecular charge-transfer interaction.
- ブンシナイ デンカ イドウ ソウゴ サヨウ オ モツ タンソ ヨウイオン
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This article deals with the recent development in the synthetic study of hydrocarbon systems composed of a stable carbocationic unit as an acceptor and a neutral π-electronic unit as a donor. Synthesis of such systems, which are defined as “undissociable charge-transfer (CT) complexes”, is important in clarifying the intramolecular π-electronic interaction in the corresponding neutral systems and correlating it with the molecular geometry. The reported carbocations are roughly classified according to the dihedral angle between the donor and acceptor units as follows : [nm] cyclophane systems, 1, 8-disubstituted naphthalenes, janusene systems, 1, 2-disubstituted benzenes, and bicyclic systems related to triptycene or barrelene. The structural effects upon the observed intramolecular CT absorption, and upon the cation stabilization by through-space π-electron donation, are discussed together with the synthetic method for each of the cations. Some limited examples of the carbanions, which might have the intramolecular π-electronic interaction, are also surveyed.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 45 (9), 850-862, 1987
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390282680287772288
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- NII論文ID
- 130000931165
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 3144112
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- CiNii Articles
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- 使用不可