Ｐｄ?QＩＩ?R‐ＰＰｈ?S３?Tを用いるＣＯそう入反応

DOI Web Site

書誌事項

タイトル別名
  • The Insertion of Carbon Monoxide by Use of Pd<SUP>II</SUP> and PPh<SUB>3</SUB>
  • Pd2 PPh3 オ モチイル CO ソウニュウ ハンノウ

この論文をさがす

抄録

It has been so far reported that the reaction of carbon monoxide with aryl or vinyl halides in the presence of alcohol or amine smoothly proceeded under atmospheric pressure by use of a catalytic amount of PbII and PPh3 to give esters or amines in good yields. This reaction was extended by us to the synthesis of heterocyclic compounds. The aryl halide having the internal amino, hydroxy and amido groups gave the benzolactams, benzolactones and imido derivatives. A variety of heterocyclic compounds including sendaverine (alkaloid) and anthramycine derivatives (antibiotics) were synthesized by this intramolecular cyclization.

収録刊行物

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ