Chemistry of 2-Alkoxy-1, 3-benzodithioles and 1, 3-Benzodithiolylium Salts

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  • 2‐アルコキシ‐1,3‐ベンゾジチオールおよび1,3‐ベンゾジチオリリウム塩の化学
  • 2 アルコキシー1 3 ベンゾジチオール オヨビ 1 3 ベンゾジチオリリウム

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Abstract

Recently 2-alkoxy-1, 3-benzodithioles have become readily obtainable by the reaction of benzyne (conveniently generated frome anthranilic acid) on carbon disulfide in the presence of alcohols, and thus now 1, 3-benzodithiolylium salts can be easily prepared from them. Recent synthetic studies with these reagents are reviewed. The review also includes the problem of aromaticity of 1, 3-benzodithiolylium salts and related compounds.

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