書誌事項
- タイトル別名
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- Nucleophilic Substitution Reaction via One Electron Transfer Processes
- イチデンシ イドウ オ トモナウ キュウカクテキ チカン ハンノウ
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説明
A new type of nucleophilic substitution reaction is described. These reactions proceed by a multistage pathway involving radical anions and free radicals as intermediates. They occur readily under mild conditions to give good yields of products, and in contrast to SN 2 displacement, they are insensitive to steric hindrance. Therefore, these reactions are valuable for the synthesis of highly branched structure. A number of examples of substitution at an aromatic carbon or at a vinylic carbon are also described. The synthesis of cephalotaxine has been achieved by intramolecular nucleophilic aromatic substitution of an enolate anion. A new olefin synthesis by one electron transfer processes is also described.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 35 (3), 165-175, 1977
公益社団法人 有機合成化学協会
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キーワード
詳細情報 詳細情報について
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- CRID
- 1390282680288765440
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- NII論文ID
- 130000924497
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 1819170
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可