書誌事項
- タイトル別名
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- Reaction of ε- Caprolactone with Alkali Cyanide
- イプシロン-カプロラクトン ト シアンカ アルカリ ノ ハンノウ
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説明
6-Cyanohexanoic acid was prepared by the reaction of ε-caprolactone with alkali cyanide in the presence of a certain catalyst.<BR>As the catalyst of this reaction, KI, NaI, I2 and NH4I, gave good results. The highest yield of the acid was 65%.<BR>ε-Caprolactone polymer reacted in the same manner as the monomer, but its cyclic dimer gave the cyano acid in only 35% yield.<BR>5-Hexenoic acid and pimelonitrile were obtained as by-products.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 31 (11), 920-923, 1973
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390282680288777856
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- NII論文ID
- 130000925861
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 7651506
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可
