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- MATSUBARA Yoshiharu
- Department of Applied Chemistry, Faculty of Science and Technology, Kinki University
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- YAMAMOTO Shigemi
- Department of Applied Chemistry, Faculty of Science and Technology, Kinki University
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- TORII Yasuhiro
- Department of Applied Chemistry, Faculty of Science and Technology, Kinki University
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- MINEMATSU Wasaku
- Shimamoto Oil Co. Ltd.
Bibliographic Information
- Other Title
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- アルキルテルペニルマレエートと各種ジエンとのDiels-Alder付加体
- アルキルテルペニルマレエート ト カクシュ ジエン ト ノ Diels-Alder フカタイ
- Studies on Surfactants Containing Terpenyl Group II
- テルペニル基を有する界面活性剤合成に関する研究 (第2報)
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Description
The adducts were obtained from various dienes and alkyl isobornyl maleates (2) in high yields.<BR>These adducts containing terpenyl groups were thought to be valuable as intermediates for anionic or nonionic surfactants.<BR>Diels-Alder reactions of various dienes [1, 3-butadiene (1), isoprene (4), cyclopentadiene (6), 1, 3-p-menthadiene (8), alloocimene (10)] with these maleates (2) were carried out in an autoclave or by refluxing.<BR>Addition reactions of (2) with (1), (4), (6), (8), (10) yielded a cyclohexa-4-ene-1, 2-dicarboxylic acid alkyl-isobornyl-ester (3), 4-methyl-cyclohexa-4-ene-1, 2-dicarboxylic acid-alkyl-isobornyl-ester (5), bicyclo [2.2.1] -hept-5-ene-2, 3-dicar-boxylic acid-alkyl-isobornyl-ester (7) and 1-isopropyl-4-methylbicyclo [2.2.2] -oct-5-ene-2, 3-dicarboxylic acid-alkyl-isobornyl-ester (11), respectively.<BR>(alkyl; ethyl, n-butyl, 2-ethyl-hexyl)
Journal
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- Journal of Synthetic Organic Chemistry, Japan
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Journal of Synthetic Organic Chemistry, Japan 30 (9), 813-817, 1972
The Society of Synthetic Organic Chemistry, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282680288905472
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- NII Article ID
- 130000926072
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- NII Book ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL BIB ID
- 7651466
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed