書誌事項
- タイトル別名
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- Approach to the Synthesis of Novel Doubly Bonded Systems between Heavier Group 15 Elements
- シンキナ コウシュウキ 15ゾク ゲンソ テイハイイ カガクシュ エノ アプローチ
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There has been much interest in the synthesis and properties of doubly bonded systems between heavier group 15 elements, heavier analogues of azo-compounds (dipnictenes), from the standpoints of fundamental and material chemistry since the first synthesis of a kinetically stabilized diphosphene, MesP = PMes (Mes=2, 4, 6-tri-t-butylphenyl), reported by Yoshifuji and his coworkers. We have also succeeded in the synthesis of the first stable distibene (RSb = SbR) and dibismuthene (RBi=BiR) by taking advantage of efficient steric protection groups, 2, 4, 6-tris [bis (trimethylsilyl) methyl] phenyl (Tbt) and 2, 6-bis [bis (trimethylsilyl) methyl] -4- [tris (trimethylsilyl) methyl] phenyl group (Bbt), and revealed their properties systematically. Nowadays, several types of synthetic methods have been established for dipnictenes, and double-bond compounds with various combination of heavier group 15 elements have been synthesized and isolated by utilizing kinetic stabilization. In this paper, we report the synthetic studies on the kinetically stabilized dipnictenes.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 65 (7), 688-699, 2007
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390282680289330944
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- NII論文ID
- 10019519878
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- NII書誌ID
- AN0024521X
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- COI
- 1:CAS:528:DC%2BD2sXotFeis7k%3D
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 8887389
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 使用不可