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- 土本 晃久
- 明治大学理工学部応用化学科
書誌事項
- タイトル別名
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- Studies on Carbon-Carbon Bond Forming Reactions Utilizing Activation of Unsaturated Hydrocarbons and Heteroaromatic Compounds by Metal Sulfonate Catalysts
- キンゾク スルホナート ショクバイ ニ ヨル フホウワ タンカスイソ オヨビ フクソ ホウコウゾク カゴウブツ ノ カッセイカ オ リヨウ シタ タンソ タンソ ケツゴウ ケイセイ ハンノウ ニ カンスル ケンキュウ
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説明
Lewis acids have been used as a mediator or a catalyst so far mainly for activation of heteroatom-containing compounds like carbonyl compounds, imines and alkyl halides. In contrast, we have been focusing on developing new carbon-carbon bond forming reactions utilizing activation of hydrocarbons by a metal sulfonate catalyst. In this context, we found that arenes as well as heterocyclic arenes add to alkynes in the presence of indium triflate [In (OTf)3, Tf=SO2CF3] as a catalyst. These findings are followed by development of facile synthesis of aryl-and heteroarylannulated [a] carbazoles by the reaction of propargyl ethers with 2-aryl-and 2-heteroarylindoles. In addition to the above reactions, metal triflates catalyzed dimerization of vinylarenes with the aid of a palladium catalyst (activation of C = C), nucleophilic substitution using a pyrrolyl group as a carbon leaving group (activation of C-C) and oxidative coupling between lactams and heterocyclic arenes (activation of C-H).
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 64 (7), 752-765, 2006
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390282680289643392
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- NII論文ID
- 10017617952
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- NII書誌ID
- AN0024521X
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- COI
- 1:CAS:528:DC%2BD28XmvFWhurw%3D
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- ISSN
- 18836526
- 15222667
- 00379980
- 09317597
- http://id.crossref.org/issn/00379980
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- NDL書誌ID
- 8032334
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- 本文言語コード
- ja
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- 資料種別
- journal article
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- データソース種別
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- JaLC
- NDLサーチ
- Crossref
- CiNii Articles
- KAKEN
- OpenAIRE
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- 抄録ライセンスフラグ
- 使用不可
