書誌事項
- タイトル別名
-
- Synthesis and Functions of Optically Active Helical Conjugated Polymers
- コウガク カッセイ ラセン キョウヤク コウブンシ ノ ゴウセイ ト キノウ
この論文をさがす
抄録
This article reviews the secondary structures, properties, and functions of helical polyacetylenes substituted with optically active groups, including cis-stereoregular poly (1-methylpropargyl ester) s, poly (N-alkynylamide) s, and poly (alkynamide) s synthesized by the polymerization using rhodium catalysts. The polymers take tightly twisted cis-cisoidal and loosely twised cis-transoidal helices according to the substituents and media, some of which undergo reversible transformation of helical sense with external stimuli such as temperature and pH. The helical polymers are applicable to chiral recognition materials and catalyts for asymmetric synthesis.
収録刊行物
-
- 有機合成化学協会誌
-
有機合成化学協会誌 66 (8), 757-764, 2008
公益社団法人 有機合成化学協会
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390282680289848192
-
- NII論文ID
- 10024278082
-
- NII書誌ID
- AN0024521X
-
- COI
- 1:CAS:528:DC%2BD1cXpvF2kurY%3D
-
- ISSN
- 18836526
- 00379980
-
- NDL書誌ID
- 9619076
-
- 本文言語コード
- ja
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可