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- Takagi Toru
- Faculty of Engineering, Nagoya University
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- KOBAYASHI Minoru
- Faculty of Engineering, Nagoya University
Bibliographic Information
- Other Title
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- 過酸型ポリマー(第3報)
- カサンガタ ポリマー 3 カサンガタ ポリ-p-ビニル アンソクコウサン ノ セイゾウ ト ソノ エポキシカ エ ノ リヨウ
- Preparation of Peracid Type Poly-p-vinyl Benzoic Acid and its Application to Epoxidation
- 過酸型ポリ-<I>p</I>-ビニル安息香酸の製造とそのエポキシ化への利用
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Description
Authors synthesized poly-p-vinyl benzoic acid-ion exchange resin which was converted to the peracid type resin by using hydrogen peroxide and methanesulfonic or p-toluenesulfonic acid. The peracid type resin of oxidation capacity 2.13 m eq / g was obtained and the conversion of COOH to COOOH was 48.4% in the best condition. The conversion of COOH to COOOH increased from 15 to 30% with increase in the cross-linking degree from 1 to 41%. The conversion rate was relatively slow as comparing with that observed in the case of peracid type XE-89, but the loss in the conversion was little. The stability in the air was better than that in the case of peracid type XE-89, but worse at 40°C in benzene, methanol and dioxane. Cyclohexene and methyl oleate were epoxidized by the peracid type resin in the yields of 5060%.
Journal
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- Journal of Japan Oil Chemists' Society
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Journal of Japan Oil Chemists' Society 16 (8), 462-467, 1967
Japan Oil Chemists' Society
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Details 詳細情報について
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- CRID
- 1390282680308318592
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- NII Article ID
- 130001021638
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- NII Book ID
- AN00245435
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- ISSN
- 0513398X
- 18842003
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- NDL BIB ID
- 8467387
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed