ヨウ素あるいはヨウ化水素の存在下におけるオクタデカジエン酸メチルの加熱反応

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書誌事項

タイトル別名
  • Thermal Reaction of Methyl Octadecadienoates in the Presence of Iodine
  • ヨウソ アルイハ ヨウカ スイソ ノ ソンザイカ ニ オケル オクタデカジエン
  • On the Formation of Methyl Octadecenoate
  • オクタデセン酸メチルの生成について

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説明

Thermal reaction of methyl linoleate in the presence of iodine was carried out under various conditions, and the relation between the amount of the methyl linoleate decreased and the amounts of the methyl octadecenoates and of the methyl conj. octadecadienoates formed was investigated. Moreover, the reactions of methyl linoleate with hydrogen iodide and of methyl 9, 11-octadecadienoate with hydrogen iodide were carried out, and the double bond distributions of methyl octadecenoates formed by the reactions were analyzed, respectively.<BR>The results indicated that in the case of methyl linoleate, methyl octadecenoates were mainly obtained by 1, 2-addition of hydrogen iodide to conj. dienes formed by the isomerization of methyl linoleate and subsequent displacement of iodo group with hydrogen.

収録刊行物

  • 油化学

    油化学 25 (7), 393-398, 1976

    公益社団法人 日本油化学会

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