The Compositions of the Reaction Products of Phosphorus Pentoxide with Alcohols

  • OKAMOTO Yoshiki
    The Institute of Scientific and Industrial Research, Osaka University
  • SAKURAI Hiroshi
    The Institute of Scientific and Industrial Research, Osaka University

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  • アルコールと五酸化リンの反応生成物の組成
  • アルコール ト 5サンカ リン ノ ハンノウ セイセイブツ ノ ソセイ

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Three well separated peaks assigned to isolated orthophosphate and end, and middle phosphates groups in linear polyphosphoric acid were found in 31p NMR spectra of the reaction mixtures. <BR>Relative proportions of these structural building units as well as orthophosphate and unreacted alcohol as a function of the ROH/P4O10 mole ratio were determined. The results obtained were discussed.

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