The Reaction of Vinylmagnesium Chloride with Cyclic Carboxylic Acids and Their Methyl Esters

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  • WATANABE Shoji
    Departmeut of Applied Chemistry, Faculty of Engineering, Chiba University
  • FUJITA Tsutomu
    Departmeut of Applied Chemistry, Faculty of Engineering, Chiba University
  • SUGA Kyoichi
    Departmeut of Applied Chemistry, Faculty of Engineering, Chiba University
  • SAITO Norio
    Departmeut of Applied Chemistry, Faculty of Engineering, Chiba University

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Other Title
  • 二, 三の環状カルボン酸およびそのエステルとビニルマグネシウムクロリドの反応
  • 2 3 ノ カンジョウ カルボンサン オヨビ ソノ エステル ト ビニル マグ

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Description

Reaction of vinylmagnesium chloride v ith cyclic carboxylic acids and their methyl esters produces a mixture of vinylketone and divinylcarbinol. For example, from 2-furoic acid, a mixture of 3- (2'-furyl) -3-hydroxy-1, 4-pentadiene, 1- (2'-furyl) -4-penten-1-one, and 1- (2'-furyl) -2-propen-1-one was obtained in good yield.

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