Oxidation of Hydrocarbons Catalyzed by π-C<SUB>3</SUB>H<SUB>5</SUB>Fe(CO)<SUB>3</SUB>B<SUB>1</SUB>

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  • OHKATSU Yasukazu
    Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo
  • OKUYAMA Toshio
    Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo
  • OSA Tetsuo
    Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo

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Other Title
  • π-C<SUB>3</SUB>H<SUB>5</SUB>Fe(CO)<SUB>3</SUB>Brを触媒とする炭化水素の酸化
  • パイ C3H5Fe Co 3Br オ ショクバイ ト スル タンカ スイソ ノ

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Abstract

It was found that π-C3H5Fe(CO)3Br catalyzed the autoxidation of hydrocarbons. The active species of the catalyst was kinetically estimated to be an oxygen complex, namely π-C3H5Fe(CO)3O2, which was formed by the reaction of π-C3H5Fe(CO)3Br with oxygen. The oxygen activated on the π-allyl complex was able to undergo hydrogen abstraction reaction or addition reaction to the double bond of substrates.

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