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- HIRAI Choichiro
- Faculty of Science & Engineering, Nihon University
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- WADA Masaru
- Faculty of Science & Engineering, Nihon University
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- Matsumoto Taro
- Faculty of Science & Engineering, Nihon University
Bibliographic Information
- Other Title
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- オレイン酸とホルムアルデヒドとの反応
- オレインサン ト ホルムアルデヒド ト ノ ハンノウ
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Description
Condensation products of oleic acid and paraformaldehyde in acetic acid solution were saponified and then fractionated by recrystallization, and the following two substances were obtained [1 part of oleic acid reacted with 2 parts of formaldehyde effectively in 1 hr when 1% of HClO4 was used as a catalyst (Fig. 3)].<BR>One of them had mp 117-118°C and seemed to have pyranol-4 structure because of its characteristics (Table 1 & Fig.-1) and it was considered as 3-octyl-4-hydroxy-5-carboxyhexyltetrahydropyran (or 3-heptyl-4-hydroxy-5-carboxyheptyltetrapyran). Pigulevskii assumed in his report about the same reaction that the product had pyranol-3 structure.<BR>And the other was C18H36O3, mp 70-71°C, A.V. 184.5, and from the IR spectrum (shown in Fig.-2), it was considered as monohydroxystearic acid (mixture of 9-and 10-hydroxy acids).<BR>As the catalyzers, perchloric acid was most effective, and sulfuric acid and borontrifluoride etherate were also fairly effective (Table 3).
Journal
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- Journal of Japan Oil Chemists' Society
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Journal of Japan Oil Chemists' Society 12 (4), 201-205, 1963
Japan Oil Chemists' Society
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Details 詳細情報について
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- CRID
- 1390282680309444608
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- NII Article ID
- 130001005512
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- NII Book ID
- AN00245435
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- ISSN
- 0513398X
- 18842003
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- NDL BIB ID
- 9214125
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed