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- YAMASHITA Masakazu
- Department of Applied Chemistry, Doshisha University
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- TASHIKA Haruyoshi
- Department of Applied Chemistry, Doshisha University
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- NAKANOBO Takashi
- Department of Applied Chemistry, Doshisha University
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- ITOKAWA Mayumi
- Department of Applied Chemistry, Doshisha University
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- SUEMITSU Rikisaku
- Department of Applied Chemistry, Doshisha University
Bibliographic Information
- Other Title
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- アシルカルボニル鉄酸塩とメチルビニルケトンの反応による1,4-ジケトンの合成
- アシルカルボニル テツ サンエン ト メチルビニルケトン ノ ハンノウ ニ ヨ
- Application to the Synthesis of <I>cis</I>-Jasmone and Dihydrojasmone
- <I>cis</I>-ジャスモンとジヒドロジャスモン合成への応用
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Abstract
The reactions of acylcarbonylferrates with methyl vinyl ketone were investigated and found to result in the formation of 1, 4-diketones in good yields under mild reaction conditions, <BR>R-Br K2Fe(CO)4→K+[RCOFe(CO)3L]- CH2=CHCOCH3 →R-COCH2CH2COCH3<BR>The reactions were variously affected accodrding to the solvents used. Dipolar aprotic solvents such as N, N-dimethylacetamide promoted the reactions but in tetrahydrofuran, they did not proceed.<BR>Using the present method, important perfume substances such as cis-jasmone and dihydrojasmone could be prepared in good over-all yield in one pot.
Journal
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- Journal of Japan Oil Chemists' Society
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Journal of Japan Oil Chemists' Society 37 (4), 250-254, 1988
Japan Oil Chemists' Society
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Details 詳細情報について
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- CRID
- 1390282680310572160
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- NII Article ID
- 130001020173
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- NII Book ID
- AN00245435
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- ISSN
- 0513398X
- 18842003
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- NDL BIB ID
- 3183696
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed