Synthesis and Surface Active Properties of Novel Fluoroalkylated Acrylic Acid Co-oligomers Containing Dimethylsilicone Segments

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  • 新規なジメチルシリコーンセグメントを有するフルオロアルキル基含有アクリル酸コオリゴマーの合成とその表面活性
  • シンキ ナ ジメチル シリコーン セグメント オ ユウスル フルオロアルキルキ

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The reactions of fluoroalkanoyl peroxides with acrylic acid and dimethylsilicones possessing one vinyl or one methacryloxypropyl end-group have been found to afford new fluoroalkylated acrylic acid cooligomers containing dimethylsilicone segments. These fluorosilicone co-oligomers were shown to be soluble in both water and common organic solvents and to be able to reduce the surface tension of water and m-xylene effectively. Additionally, these co-oligomers were found to exhibit a strong oleophobic property on their surface though possessing long dimethylsilicone chains.

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