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- 椎名 久子
- 工業技術院化学技術研究所
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- 窪田 安彦
- 工業技術院化学技術研究所
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- 間室 秀夫
- 工業技術院化学技術研究所
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- 中里 敏
- 工業技術院化学技術研究所
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- OOI Tian Lye
- Palm Oil Research Institute of Malaysia (PORIM)
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- ONG Augustine Soon Hock
- Palm Oil Research Institute of Malaysia (PORIM)
書誌事項
- タイトル別名
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- Oxidative Cleavage of Palm Stearin Catalyzed by Metal (II) Ion-Exchanged Zeolites
- キンゾク 2 イオン コウカン ゼオライト オ ショクバイ ト スル パームス
- A Preliminary Screening of Catalysts
- 触媒の予備探索
この論文をさがす
説明
Metal (II) ion-exchanged 5A, Y, and X type zeolites were screened to find effective catalysts for oxidative cleavage of palm stearin into mono- and dibasic acids with middle carbon chains.<BR>The formation of carboxylic acids was followed by 1H NMR spectrometry. When one reaction was recognized to form volatile material more than the others, it was carried out on a larger scale to collect the volatile material. This material was submitted to GC-MS spectral analysis for identification of individual components.<BR>The formation of carboxylic acid was confirmed in the case of products obtained by catalysts such as Mn (II) -5A and Co (II) -Y, but the amount of each was quite small. Analytical results on the volatile materials showed Mn (II) -5A and Co (II) -Cu (II) -Y to contribute to the formation of carbo-xylic acids and aldehydes, respectively.
収録刊行物
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- 油化学
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油化学 35 (5), 349-353, 1986
公益社団法人 日本油化学会
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詳細情報 詳細情報について
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- CRID
- 1390282680312315648
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- NII論文ID
- 130001019791
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- NII書誌ID
- AN00245435
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- ISSN
- 0513398X
- 18842003
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- NDL書誌ID
- 3082271
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可