書誌事項
- タイトル別名
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- Molecular Recognition of Cyclophanes as Artificial Receptors
- ジンコウ レセプター トシテノ シクロファンルイ ノ ブンシ ニンシキ
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説明
Novel cage-type cyclophanes bearing L-and D-valine residues and capable of providing a three-dimensionally extended cavity were prepared in order to simulate specific functions of naturally occurring receptors. The cage-type hosts provide relatively apolar microenvironments, which are well shielded from the bulk aqueous phase, for hydrophobic guests. Moreover, the cage-type hosts bearing L-and D-valine residues in their respective bridging segments afford S-and R-helical cavities, respectively.The helically twisted cavities of the hosts furnish conformation-enforced microenvironments for chiral recognition of enantiomeric guests, such as bilirubin-IXα, as well as diastereomeric guests, such as steroid hormones.
収録刊行物
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- 油化学
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油化学 43 (10), 760-768, 1994
公益社団法人 日本油化学会
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詳細情報 詳細情報について
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- CRID
- 1390282680312430080
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- NII論文ID
- 10006946673
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- NII書誌ID
- AN00245435
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- ISSN
- 0513398X
- 18842003
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- NDL書誌ID
- 3905631
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可