面不斉遷移金属錯体の触媒的不斉合成

DOI DOI DOI Web Site Web Site ほか2件をすべて表示 一部だけ表示 被引用文献19件 参考文献176件

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タイトル別名
  • Catalytic Asymmetric Synthesis of Planar-Chiral Transition-Metal Complexes
  • メン フセイ センイ キンゾク サクタイ ノ ショクバイテキ フセイ ゴウセイ

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説明

Although “central chirality” based on stereogenic carbon atoms is arguably the most common chiral element in organic chemistry, chiral molecules devoid of stereogenic centers play important roles in stereoselective organic transformations. Among these chiral compounds with “non-centrochirality”, planar-chiral transition-metal complexes have been utilized as chiral ligands, chiral catalysts, or chiral building blocks in asymmetric synthesis. However, enantiomerically enriched forms of these compounds are primarily obtained by rather classical methods. Examples of catalytic enantioselective induction of planar-chirality in transition-metal species have been extremely rare and still a developing area in this field. In this review article, catalytic asymmetric synthesis of various “planar-chiral transition-metal complexes” are surveyed in a comprehensive manner.

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